I created a whitepaper a while back that describes how you can use SDM Software’s free GPMC cmdlets along with our commercial GPExpert(tm) Scripting Toolkit product to automate Group Policy management using PowerShell. That whitepaper, entitled "Automating Group Policy Management" is now up on our website for download. You do have to register for it but it goes through a bunch of different scenarios, including performing basic GPO management tasks as well as using the Toolkit to audit or modify Group Policy settings across a group of GPOs.
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